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課程名稱 |
物理化學一
Physical Chemistry (Ⅰ) |
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開課學期 |
100-1 |
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授課對象 |
化學工程學系 |
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授課教師 |
戴子安 |
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課號 |
ChemE2005 |
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課程識別碼 |
504 26110 |
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班次 |
01 |
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學分 |
3 |
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全/半年 |
半年 |
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必/選修 |
必修 |
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上課時間 |
星期一3,4(10:20~12:10)星期四2(9:10~10:00) |
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上課地點 |
普303普303 |
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備註 |
本系同學儘量在初選階段選定本課程。
限本系所學生(含輔系、雙修生)
總人數上限：70人 |
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Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/1001pchemI_dai |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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為確保您我的權利,請尊重智慧財產權及不得非法影印
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課程概述 |
物理化學（一）、（二）
學分數：3、3
一、 課程大綱：
Thermodynamics
1. Zeroth Law of Thermodynamics
2. First Law of Thermodynamics
3. Second and Third Laws of Thermodynamics
4. Fundamental Equations of Thermodynamics
5. Chemical Equilibrium
6. Phase Equilibrium
7. Electrochemical Equilibrium
Quantum
9. Quantum Theory
13-14. Rotational, Vibrational and Electronic Spectroscopy
Kinetics
17. Kinetic Theory of Gases
18. Experimental Kinetics and Gas Reactions
19. Chemical Dynamics and Photochemistry
20. Kinetics in the Liquid Phase
24. Surface Dynamics
二、 教科書：Physical Chemistry, 4th Edition, by Silbey/Alberty/Bawendi, Wiley.
三、 預修課程：普通物理，普通化學
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課程目標 |
This course is an introduction to chemical thermodynamics, quantum mechanics and chemical kinetics with application to gases, solutions, phase equilibria to provide a firm foundation for understanding the physical principles that govern chemical and biological systems.
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課程要求 |
midterm exams (2) each 25%
final exam 30%
Homework + quiz (every Thursday) 20%
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預期每週課後學習時數 |
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Office Hours |
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指定閱讀 |
Textbook: Physical Chemistry, 4th Edition, by Silbey/Alberty/Bawendi, Wiley.
There is a solution manual for the textbook.
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參考書目 |
Reference books:
1. Atkins’ Physical Chemistry, 9th Edition, by Atkins and de Paula, Oxford
University Press.
2. Physical Chemistry, by Engel and Reid, Pearson Publishing.
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評量方式
(僅供參考) |
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週次 |
日期 |
單元主題 |
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第1週 |
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(一):Chapter 1 Zero Law of Thermodynamics and Equation of State 1.1 State of a System, 1.2 Zeroth Law of Thermodynamics, 1.3 and 1.4 Ideal Gas Mixture and Dalton's Law (四):1.5 Real Gases and The Virial Equation 1.6 P-V-T Surface for a One-Componet System |
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第2週 |
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一): 1.7 critical phenomena 1.8 the van der Waals 1.9 The Principle of Corresponding States (四):1.10 Partial Molar Properties, 1.11 Barometric Formula |
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第4週 |
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(一): 2.5 Various Kinds of Work 2.6 Change in State at Constant Volume 2.7 Enthalpy and Change of State at Constant Pressure (四): 2.8 Heat Capacities |
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第5週 |
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(一): 2.9 Joule-Thomson Expansion, 2.10 Adiabatic Process with Gases, 2.11 Thermochemistry (四):2.12 Enthalpy of Formation |
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第7週 |
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(一): 1st Exam; (四): 3.2 the second law of Thermodynamics |
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第8週 |
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(一): 3.3 Entropy Changes in Reversible Process 3.4 Entropy Change in Irreversible Process (四): 3.5 Entropy of Mixing Ideal Gases 3.6 Enropy and Statistical Probability |
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第10週 |
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(一): 4.2 Definition of Additional Thermodynamic Potentials Using Legendre Transforms (四):4.3 Effect of Temperature on the Gibbs Energy 4.4 Effect of Pressure on the Gibbs Energy |
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第11週 |
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(一): 4.5 Fugacity and Activity 4.6 The Significance of the Chemical Potential (四):Additive of Partial Molar Properties with Applications to Ideal Gases |
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第12週 |
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(一): 4.8 Gibbs-Duhem Equation 4.9 Special Topic: Maxwell relation, Chapter 5 Chemical Equilibrium 5.1 Derivation of the General Expression (四):5.2 Equilibrium Constant Expression for Gas Reactions |
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第13週 |
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(一): 2nd Exam (四):5. 3 Determination of Equilibrium Constant |
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第14週 |
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(一):5.4 Use of Standard Gibbs Energies of Formation to Calculate Equilibrium Constants 5.5 Effect of Temperature on Equilibrium Constants 5.6 Effect of Pressure, Initial Composition, and Insert Gases on the Equilibrium Composition 5.7 Equilibrium Constants for Gas Reactions Written in Terms of Concentrations (四): 5.8 Heterogeneous Reactions 5.9 Phase Components, Degree of Freedom and the Phase Rule |
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第15週 |
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(一): Chapter 6 Phase Equilibrium 6.1 Phase Diagrams of One-Component Systems (四): 6.2 The Clapeyron Equation 6.3 The Clausius-Clapeyron Equation |
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第16週 |
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(一): 6.4 Vapor-Liquid Equilibriumof Binary Liquid Mixture 6.5 Vapor Pressure of Nonideal Mixture and Henry's Law (四): 6.6 Activity Coefficients |
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第17週 |
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(一):6.7 Colligative Properties 6.8 Two Component Systems Consisting of L/L, V/L and L/S Phases (四):6.9 Effect of Surface Tension on the Vapor Pressure |
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